Unit 7 The P Block Elements (Intext Questions-1)

Intext Questions

7.1 Why are pentahalides of P, As, Sb and Bi more covalent than their trihalides?

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Answer

In pentahalides, the oxidation state is +5 and in trihalides, the oxidation state is +3 . Since the metal ion with a high charge has more polarizing power, pentahalides are more covalent than trihalides.

7.2 Why is $\mathrm{BiH_3}$ the strongest reducing agent amongst all the hydrides of Group 15 elements ?



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