NEET Solved Paper 2016 Question 24

Question: Consider the nitration of benzene using mixed conc. $ {H_2}S{O_4} $ and $ HN{O_3}\text{.} $ If a large amount of $ KHS{O_4} $ is added to the mixture, the rate of nitration will be:-

Options:

A) faster

B) slower

C) unchanged

D) doubled

Show Answer

Answer:

Correct Answer: B

Solution:

Slower, as large amount of $ HSO_4^{-} $ will decrease ionisation of $ {H_2}S{O_4} $ that result in lesser ionization of nitric acid and lesser formation of nitronium ion $ [NO _2^{+}] $



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